 Solution

An electron accelerated in an ion's Coulomb field emits bremsstrahlung. Both electron states are unbound, giving free-free radiation rather than a discrete bound-state line. Averaging over a Maxwellian electron distribution gives an optically thin spectral emissivity with dependenceHere $C_{\mathrm{ff}}$ depends on the emissivity convention, and the Gaunt factor supplies the quantum correction. No numerical emissivity normalization is needed for these diagnostics. For a mixture, sum $Z_i^2{n}_i$ over ion species. The bolometric emissivity is proportional to $n_e\sum Z_i^2{n}_i{T}^{1/2}$ with a frequency-averaged Gaunt factor. Thermal electron speeds control the spectrum while the encounter rate supplies its density-squared dependence.

temperature can be measured from the high-energy exponential cutoff at photon energy of order $k_{B}T$, provided the spectrum spans that turnover and foreground absorption and nonthermal contamination are modelled. At radio frequencies $h\nu \ll k_{B}T$, the exponential is nearly one, so the optically thin continuum is a poor thermometer by slope alone. Kirchhoff's law, ${\alpha }_{\nu }=j_{\nu }/B_{\nu }$, and the Rayleigh-Jeans law give ${\alpha }_{\nu }\propto n_e{n}_i{T}^{-3/2}{\nu }^{-2}{\bar{g}}_{\mathrm{ff}}$ for an isothermal thermal plasma. The transfer solution isin the radio limit. A resolved optically thick region therefore measures its electron temperature through brightness temperature, if it fills the beam. The turnover between thick and thin emission constrains the line-of-sight emission measure $\mathrm{EM}=\int n_e^{2}dl$ for a hydrogen-dominated fully ionized plasma. In the thin regime $T_b\simeq T{\tau }_{\nu }$, rather than $T_b=T$. The slowly varying Gaunt factor gives a nearly flat optically thin radio flux-density spectrum, in contrast to the ${\nu }^2$ thick limit at fixed projected area.^[ref]

To obtain density, one also needs geometry. An angular extent and independent distance give a transverse size; an assumed shape provides a depth or volume. For approximately uniform emitting gas with astrophysical volume filling factor $f_V$, $L_{\mathrm{ff}}\propto n_e^2{f}_{V}V{T}^{1/2}$, so $n_e\propto [L_{\mathrm{ff}}/(f_{V}V{T}^{1/2}){]}^{1/2}$. Alternatively a measured column emission measure and assumed path length give an rms density. Clumping raises the mean squared density relative to the square of the mean: the inferred value is not automatically the mean gas density. Free-free brightness alone does not uniquely determine temperature, density and physical size. Resolved imaging, a distance, optical-depth information or an independent column-density diagnostic is needed to remove those degeneracies. Cluster SZ data are complementary because their leading signal depends on $\int n_e{T}_{e}dl$, whereas free-free emission depends on density squared. Metal lines, unresolved temperature structure, foreground absorption, synchrotron emission and background subtraction must be controlled before attributing the continuum to a single thermal component.