 Solution

A reachable set consists of states obtainable from one specified initial state using admissible inputs and allowed durations. Controllability means that every target in the declared state space is reachable from every initial state there; the declared space and time convention are essential.

For a closed quantum system, let $U_f$ solve the controlled Schrödinger equation with $U_f(0)=I$. The propagator and state reachable sets areA pure-state version acts on normalized vectors up to global phase. Pure-state controllability makes every pure target accessible; unitary operator controllability permits every desired coherent process, with global phase treated according to the definition.

For mixed states, density operator controllability means transitivity on each unitary orbit of a density operator, not access to all density operators regardless of spectrum. The Dynamical Lie algebra generated by $-i{H}_0,-i{H}_1,\dots$ describes the accessible connected unitary transformations under the usual unconstrained-time control assumptions. Conserved quantities or restricted controls can shrink the reachable set. Thus successful preparation of one state is weaker than implementation of an arbitrary gate on all inputs, and coherent controllability does not imply purification.