 Solution

Let $A$ be a skew-symmetric matrix. For every real vector $x$, the real scalar $x^{T}Ax$ equals its own transpose, butHence $x^{T}Ax=0$. If $Av=\lambda v$ is a real eigenvector equation with $v\ne 0$, it follows thatso $\lambda =0$. If $A$ is a diagonalisable matrix over $\mathbb{R}$, it has a real basis of eigenvectors, all with eigenvalue zero. Thus $A$ vanishes on a basis and $\boxed{A=0_n}$.

The field matters: a nonzero real skew-symmetric matrix can be a diagonalisable matrix over the complex numbers, for example $\left(\begin{array}{cc}0& -1\\ 1& 0\end{array}\right)$ with eigenvalues $i,-i$.