 Solution

For a nonzero admissible radial profile define the radial diffusion Rayleigh quotientMinimizing the numerator subject to ${\int }_0^{1}r{R}^{2}dr=1$ introduces a multiplier $\nu$. The Euler-Lagrange equation for $r\kappa R^{\prime 2}-\nu r{R}^2$ isThe allowed variations vanish at $r=1$, and the natural condition at the centre is zero radial flux. Thus the minimum, when attained, is the smallest decay eigenvalue ${\nu }_0$. Equivalently, expansion in weighted-orthogonal eigenfunctions makes $\mathcal{R}[R]$ a weighted average of their decay eigenvalues. The Rayleigh-Ritz variational principle therefore givesAdmissible trial functions must obey the outer boundary condition, be nonzero and have finite weighted norm and energy; they need not solve the differential equation. If the diffusion operator has no lowest eigenfunction, the same variational argument bounds the infimum of its spectrum. Existence of a fundamental diffusion mode is an additional assumption for strongly vanishing diffusivity, not a consequence of the identity alone.