For a nonzero admissible radial profile define the radial diffusion Rayleigh quotientMinimizing the numerator subject to introduces a multiplier . The Euler-Lagrange equation for isThe allowed variations vanish at , and the natural condition at the centre is zero radial flux. Thus the minimum, when attained, is the smallest decay eigenvalue . Equivalently, expansion in weighted-orthogonal eigenfunctions makes a weighted average of their decay eigenvalues. The Rayleigh-Ritz variational principle therefore givesAdmissible trial functions must obey the outer boundary condition, be nonzero and have finite weighted norm and energy; they need not solve the differential equation. If the diffusion operator has no lowest eigenfunction, the same variational argument bounds the infimum of its spectrum. Existence of a fundamental diffusion mode is an additional assumption for strongly vanishing diffusivity, not a consequence of the identity alone.
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