 Solution

For constant diffusivity, the trial Rayleigh quotient simplifies toIts derivative is $1-2/q^2$, so its only positive critical point is $q=\sqrt{2}$. The second derivative is $4/q^3>0$; also the quotient diverges as $q\downarrow 0$ or $q\to \infty$. Therefore this is the global optimum within the trial family:The two requested profiles areThe initial radial graph decreases from one at the centre to zero at the rim, has horizontal tangent at the centre, and is concave downward for $0<r<1$. The central temperature decreases exponentially from one to zero, with initial time derivative $-(3+2\sqrt{2})$. These are trial profiles, not exact solutions of the full heat equation. Although the radial trial function is not twice differentiable at the centre, it has finite weighted energy and belongs to the variational trial class used by the Rayleigh-Ritz variational principle.