Solution

ID: past-exam-of-the-physics-b-course-of-the-university-of-cambridge/2013/paper-2/section-a/a4/solution

Use the rotating reference frame equilibrium model, in which the centrifugal potential energy of a particle of mass is . The Boltzmann distribution then gives
Define the concentration ratio as . At the axis,
Thus the axis favours the lighter species. The expression assumes a dilute classical mixture at one temperature, equilibrium in the rotating reference frame, and sampling sufficiently close to .

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