One important quantum mechanics experiment, which using quantum effects explain the dependency of specific heat capacity on temperature, an effect which is not present in the Dulong-Petit law.
This is the solid-state analogue to the black-body radiation problem. It is also therefore a quantum mechanics-specific phenomenon.
It can be seen as the limit case of an Einstein solid at high temperatures. At lower temperatures, the heat capacity depends on temperature.
Wikipedia mentions that it is completely analogous to Planck's law.
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Specific heat capacity is heat capacity per unit mass:Its units are , and the constraint remains part of the definition. In particular, specific heat capacity at constant volume and specific heat capacity at constant pressure are different responses. For homogeneous material, doubling the mass doubles its heat capacity while leaving its specific heat capacity unchanged. [ref]
As an illustrative material model, give a fixed-volume body mass and constant specific heat capacity at constant volume . With no phase transition and no other work, increasing its uniform temperature by requiresThese stipulated values describe no measured substance. The right panel of the diagram in heat capacity shows the straight line : a temperature increase of takes of heat. If the specific heat capacity at constant volume depends on temperature, use instead. The corresponding fixed-pressure calculation uses specific heat capacity at constant pressure and gives under the assumptions in heat capacity.
Choosing between specific heat capacity, molar heat capacity and volumetric heat capacity is choosing whether to compare equal mass, equal amount of substance or equal volume. A small sample with large specific heat capacity can still have less total heat capacity than a much larger sample.
Specific heat capacity, often simply referred to as specific heat, is a physical property of a substance that measures the amount of heat energy required to raise the temperature of a unit mass of that substance by one degree Celsius (or one Kelvin). The specific heat capacity is typically denoted by the symbol \( c \) and is expressed in units such as joules per kilogram per degree Celsius (J/kg·°C) or joules per kilogram per Kelvin (J/kg·K).