Condensed matter physics is one of the best examples of emergence. We start with a bunch of small elements which we understand fully at the required level (atoms, electrons, quantum mechanics) but then there are complex properties that show up when we put a bunch of them together.
Includes fun things like:
As of 2020, this is the other "fundamental branch of physics" besides to particle physics/nuclear physics.
Condensed matter is basically chemistry but without reactions: you study a fixed state of matter, not a reaction in which compositions change with time.
Just like in chemistry, you end up getting some very well defined substance properties due to the incredibly large number of atoms.
Just like chemistry, the ultimate goal is to do de-novo computational chemistry to predict those properties.
And just like chemistry, what we can actually is actually very limited in part due to the exponential nature of quantum mechanics.
Also since chemistry involves reactions, chemistry puts a huge focus on liquids and solutions, which is the simplest state of matter to do reactions in.
Condensed matter however can put a lot more emphasis on solids than chemistry, notably because solids are what we generally want in end products, no one likes stuff leaking right?
But it also studies liquids, e.g. notably superfluidity.
One thing condensed matter is particularly obsessed with is the fascinating phenomena of phase transition.
AMO is a slightly more general area than condensed matter physics, including related phenomena with smaller numbers atoms and optics. The two terms are however sometimes used as synonyms. The term AMO has gained wide usage and acceptability, see e.g.:
If Ciro had had greater foresight, this might have been what he studied at university!
Molecular beams are cool because they create a one dimensional flow of molecules, which makes it easier to observe certain single-molecule effects, as it removes the multi-particle issues from experiments.
Key molecular beam experiments include:
- Stern-Gerlach experiment, which confirmed the existence of spin
- Rabi's NMR experiment, which confirmed the existence of nuclear spin
The center piece of the control system of atomic clocks is a molecular beam.
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Bibliography:
Previously on EdX: www.edx.org/learn/quantum-physics-mechanics/delft-university-of-technology-topology-in-condensed-matter-tying-quantum-knots "DelftX: Topology in Condensed Matter: Tying Quantum Knots".
But then they regained their sanity and put the source code on GitHub: github.com/topocm/topocm_content and is CC BY-SA.
How are the bands measured experimentally?
Why are there gaps? Why aren't bands infinite? What determines the width of gaps?
Bibliography:
- Applications of Quantum Mechanics by David Tong (2017) Chapter 2 "Band Structure"
Ciro Santilli distinctly remembers being taught that at basic electrical engineering school during Ciro Santilli's undergrad studies at the University of São Paulo.
It really allows you to do alternating current calculations much as you'd do DC calculations with resistors, quite poweful. It must have been all the rage in the 1950s.
If you adda bit of impurities to certain materials, at low temperatures of a few Kelvin their resistivity actually starts increasing if you go below a certain critical temperature.
The basis of 1970-20XX computers, gotta understand them I guess?
Most notable example: gallium arsenide, see also: gallium arsenide vs silicon.
An important class of semiconductors, e.g. there is a dedicated III-V lab at: École Polytechnique: www.3-5lab.fr/contactus.php
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Experiments:
- "An introduction to superconductivity" by Alfred Leitner originally published in 1965, source: www.alfredleitner.com/
- Isotope effect on the critical temperature. hyperphysics.phy-astr.gsu.edu/hbase/Solids/coop.html mentions that:
If electrical conduction in mercury were purely electronic, there should be no dependence upon the nuclear masses. This dependence of the critical temperature for superconductivity upon isotopic mass was the first direct evidence for interaction between the electrons and the lattice. This supported the BCS Theory of lattice coupling of electron pairs.
Actually goes into the equations.
Notably, youtu.be/O_zjGYvP4Ps?t=3278 describes extremely briefly an experimental setup that more directly observes pair condensation.
Lecture notes:
Media:
- Cool CNRS video showing the condensed wave function, and mentioning that "every pair moves at the same speed". To change the speed of one pair, you need to change the speed of all others. That's why there's not energy loss.
Transition into superconductivity can be seen as a phase transition, which happens to be a second-order phase transition.
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andor.oxinst.com/learning/view/article/measuring-resistance-of-a-superconducting-sample-with-a-dry-cryostat Not a video, but well done, by Oxford Instruments.
TODO!!! Even this is hard to find! A clean and minimal one! Why! All we can find are shittly levitating YBCO samples in liquid nitrogen! Maybe because liquid helium is expensive?
We know that superfluidity happens more easily in bosons, and so electrons joins in Cooper pairs to form bosons, making a superfluid of Cooper pairs!
Isn't that awesome!
There are various possibilities for the axes, but some common ones:
- temperature (T) vs magnetic field strength (B)
- temperature (T) vs proportion of each chemical element of a binary alloy
- temperature (T) vs pressure
As of 2020, basically means "liquid nitrogen temperature", which is much cheaper than liquid helium.
The dream of course being room temperature and pressure superconductor.
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Upside: superconducting above 92K, which is above the 77K of liquid nitrogen, and therefore much much cheaper to obtain and maintain than liquid helium.
Downside: it is brittle, so how do you make wires out of it? Still, can already be used in certain circuits, e.g. high temperature SQUID devices.
Discovered in 1988, the first high-temperature superconductor which did not contain a rare-earth element.
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Superconductivity is one of the key advances of 21st century technology:
- produce powerful magnetic fields with superconducting magnets
- the Josephson effect, applications listed at: Section "Applications of Josephson Junctions"
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As of 2023 the most important ones economicaly were:The main application is Magnetic resonance imaging. Both of these are have to be Liquid helium, i.e. they are not "high-temperature superconductor" which is a pain. One big strength they have is that they are metallic, and therefore can made into wires, which is crucial to be able to make electromagnetic coils out of them.
- Nb-Ti: the most widely used one. Used e.g. to create the magnetic fields of the Large Hadron Collider Up to 15 T.
- Nb-Sn: more expensive than Nb-Ti, but can reach up to 30 T.
TODO, come on, Internet!
Bibliography.
No, see: superconductor I-V curve.
Bibliography:
- physics.stackexchange.com/questions/62664/how-can-ohms-law-be-correct-if-superconductors-have-0-resistivity on Physics Stack Exchange
- physics.stackexchange.com/questions/69222/how-can-i-put-a-permanent-current-into-a-superconducting-loop
- www.quora.com/Do-superconductors-produce-infinite-current-I-V-R-R-0-How-do-they-fit-into-quantum-theory
- www.reddit.com/r/askscience/comments/dcgdf/does_superconductivity_imply_infinite_current/
- www.reddit.com/r/askscience/comments/7xhb46/what_would_happen_if_a_voltage_was_applied_to_a/
Main theory to explain Type I superconductors very successfully.
TODO can someone please just give the final predictions of BCS, and how they compare to experiments, first of all? Then derive them.
High level concepts:
- the wave functions of pairs of electrons (fermions) get together to form bosons. This is a phase transition effect, thus the specific sudden transition temperature.
- the pairs form a Bose-Einstein condensate
- once this new state is reached, all pairs are somehow entangled into one big wave function, and you so individual lattice imperfections can't move just one single electron off trajectory and make it lose energy
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Discrete quantum effect observed in superconductors with a small insulating layer, a device known as a Josephson junction.
To understand the behaviour effect, it is important to look at the Josephson equations consider the following Josephson effect regimes separately:
A good summary from Wikipedia by physicist Andrew Whitaker:
at a junction of two superconductors, a current will flow even if there is no drop in voltage; that when there is a voltage drop, the current should oscillate at a frequency related to the drop in voltage; and that there is a dependence on any magnetic field
Bibliography:
- www.youtube.com/watch?v=cnZ6exn2CkE "Superconductivity: Professor Brian Josephson". Several random excerpts from Cambridge people talking about the Josephson effect
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In 1962 Brian Josephson published his inaugural paper predicting the effect as Section "Possible new effects in superconductive tunnelling . "
In 1963 Philip W. Anderson and John M. Rowell published their paper that first observed the effect as Section "Possible new effects in superconductive tunnelling . "
Some golden notes can be found at True Genius: The Life and Science of John Bardeen page 224 and around. Philip W. Anderson commented:
As part of the course Anderson had introduced the concept of broken symmetry in superconductors. Josephson "was fascinated by the idea of broken symmetry, and wondered whether there could be any way of observing it experimentally."
The inaugural that predicted the Josephson effect.
Published on Physics Letters, then a new journal, before they split into Physics Letters A and Physics Letters B. True Genius: The Life and Science of John Bardeen mentions that this choice was made rather than the more prestigious Physical Review Letters because they were not yet so confident about the results.
Paper by Philip W. Anderson and John M. Rowell that first (?) experimentally observed the Josephson effect.
Paywalled by the American Physical Society as of 2023 at: journals.aps.org/prl/abstract/10.1103/PhysRevLett.10.230
TODO understand the graphs in detail.
They used tin-oxide-lead tunnel at 1.5 K. TODO oxide of what? Why two different metals? They say that both films are 200 nm thick, so maybe it is:
-----+------+------+-----
... Sn | SnO2 | PbO2 | Pb ...
-----+------+------------
100nm 100nm
A reconstruction of their circuit in Ciro's ASCII art circuit diagram notation TODO:
DC---R_10---X---G
There are not details of the physical construction of course. Reproducibility lol.
This is what happens when you apply a DC voltage across a Josephson junction.
It is called "AC effect" because when we apply a DC voltage, it produces an alternating current on the device.
By looking at the Josephson equations, we see that a positive constant, then just increases linearly without bound.
Therefore, from the first equation:
we see that the current will just vary sinusoidally between .
This meas that we can use a Josephson junction as a perfect voltage to frequency converter.
Wikipedia mentions that this frequency is , so it is very very high, so we are not able to view individual points of the sine curve separately with our instruments.
Also it is likely not going to be very useful for many practical applications in this mode.
An I-V curve can also be seen at: Figure "Electron microscope image of a Josephson junction its I-V curve".
If you shine microwave radiation on a Josephson junction, it produces a fixed average voltage that depends only on the frequency of the microwave. TODO how is that done more preciesely? How to you produce and inject microwaves into the thing?
It acts therefore as a perfect frequency to voltage converter.
The Wiki page gives the formula: en.wikipedia.org/wiki/Josephson_effect#The_inverse_AC_Josephson_effect You get several sinusoidal harmonics, so the output is not a perfect sine. But the infinite sum of the harmonics has a fixed average voltage value.
And en.wikipedia.org/wiki/Josephson_voltage_standard#Josephson_effect mentions that the effect is independent of the junction material, physical dimension or temperature.
All of the above, compounded with the fact that we are able to generate microwaves with extremely precise frequency with an atomic clock, makes this phenomenon perfect as a Volt standard, the Josephson voltage standard.
TODO understand how/why it works better.
Two equations derived from first principles by Brian Josephson that characterize the device, somewhat like an I-V curve:
where:
- : Josephson current
- : the Josephson phase, a function defined by the second equation plus initial conditions
- : input voltage of the system
- : current across the junction, determined by the input voltage
Note how these equations are not a typical I-V curve, as they are not an instantaneous dependency between voltage and current: the history of the voltage matters! Or in other words, the system has an internal state, represented by the Josephson phase at a given point in time.
To understand them better, it is important to look at some important cases separately:
- AC Josephson effect: V is a fixed DC voltage
Maximum current that can flow across a Josephson junction, as can be directly seen from the Josephson equations.
Is a fixed characteristic value of the physical construction of the junction.
A function defined by the second of the Josephson equations plus initial conditions.
It represents an internal state of the junction.
A device that exhibits the Josephson effect.
TODO is there any relationship between this and the Josephson effect?
Experimental observation published as Experimental Evidence for Quantized Flux in Superconducting Cylinders.
This appears to happen to any superconducting loop, because the superconducting wave function has to be continuous.
Video "Superconducting Qubit by NTT SCL (2015)" suggests that anything in between gets cancelled out by a superposition of current in both directions.
Paywalled at: journals.aps.org/prl/abstract/10.1103/PhysRevLett.7.43
The first published experimental observation of the magnetic flux quantum.
The paper that follows it in the journal is also of interest, "Theoretical Considerations Concerning Quantized Magnetic Flux In Superconducting Cylinders" by N. Byers and C. N. Yang, it starts:So there was some previous confusion about the flux quantum due to the presence of Cooper pairs or not.
In a recent experiment, the magnetic flux through a superconducting ring has been found to be quantized in units of ch/2e. Quantization in twice this unit has been briefly discussed by London' and by Onsager. ' Onsager' has also considered the possibility of quantization in units ch/2e due to pairs of electrons forming quasi-bosons.
Dumping the fitures at: archive.org/details/experimental-evidence-for-quantized-flux-in-superconducting-cylinders One day we can also dump the paper scans when it goes into the public domain in 2056! Public domain scientific paper by year.
The inverse of the magnetic flux quantum.
As mentioned in True Genius: The Life and Science of John Bardeen page 224, the idea of symmetry breaking was a major motivation in Josephson's study of the Josephson effect.
- the basis for the most promising 2019 quantum computing implementation: superconducting quantum computer
- Josephson voltage standard: the most practical/precise Volt standard, which motivated the definition of the ampere in the 2019 redefinition of the SI base units
- SQUID devices, which are:
- very precise magnetometer
- the basis for superconducting quantum computers
The most practical/precise volt standard.
It motivated the definition of the ampere in the 2019 redefinition of the SI base units
Quick NIST article about it: www.nist.gov/news-events/news/2013/04/primary-voltage-standard-whole-world (archive)
The wiki page en.wikipedia.org/wiki/Josephson_voltage_standard contains amazing schematics of the device, apparently made by the US Government.
Can be used as a very precise magnetometer.
There are high temperature yttrium barium copper oxide ones that work on liquid nitrogen.
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Two parallel Josephson junctions.
In Ciro's ASCII art circuit diagram notation:
|
+-+-+
| |
X X
| |
+-+-+
|
Specific type of Josephson junction. Probably can be made tiny and in huge numbers through photolithography.
Inward Bound by Abraham Pais (1988) page 282 shows how this can be generalized from the Maxwell-Boltzmann distribution
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TODO WTF is this? How is it built? What is special about it?
Mentioned a lot in the context of superconducting quantum computers, e.g. youtu.be/t5nxusm_Umk?t=268 from Video "Quantum Computing with Superconducting Qubits by Alexandre Blais (2012)",
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Mentioned at: Video "Quantum Computing with Light by Quantum Light University of Sheffield (2015)" youtu.be/nyK-vhoOBpE?t=185.
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www.youtube.com/watch?v=PbuiIhr0LVA 7 Different Types of Plastic and Their Uses by Orange Plastics Academy (2018) Does not mention packaging foams.