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A bimetallic nanocrystal is a crystalline particle containing two metallic chemical elements, with important dimensions on the nanoscale. Its atoms may form an alloy, chemically ordered regions, a core surrounded by a shell or spatially separated domains. Composition alone does not determine which arrangement is present.

For example, a gold–silver particle can expose a surface composition different from its bulk average. That affects surface chemistry and interaction with light. Establishing its structure requires complementary evidence: electron microscopy can reveal morphology, elemental mapping can locate the elements, and diffraction can constrain the crystal structure. These measurements answer different questions rather than providing interchangeable particle descriptions.

Kyle D. Gilroy surveyed synthetic routes and properties of bimetallic nanocrystals. Distinguishing an alloy from a core–shell particle makes the spatial arrangement of the two metals part of the material specification, alongside its overall composition.^[ref]