Charge stabilization of colloids

Like-charged colloids can resist aggregation because bringing their electric double layers together costs free energy. In DLVO theory, screened electrostatic repulsion competes with attractive Van der Waals forces. A repulsive barrier much larger than $k_{B}T$ suppresses thermally activated aggregation, although the dispersion can remain metastable. Lower ionic strength generally lengthens the Debye–Hückel screening length, while multivalent counterions or added salt shorten it and can lower the barrier. The surface charge, charge regulation and solvent-dependent attraction also matter; screening length alone does not guarantee stability.

The critical coagulation concentration is the approximate electrolyte concentration separating slow, barrier-limited aggregation from rapid aggregation of a charge-stabilized colloid. In the simplest DLVO theory, increasing salt shortens the Debye–Hückel screening length and lowers the repulsive barrier until rapid aggregation is possible. It depends on particle charge, solvent, temperature and particularly counterion valence. It is a kinetic crossover, not a universal salt concentration or necessarily an equilibrium phase boundary. Aggregation just below this crossover can be reaction limited; exactly at or above the rapid-aggregation threshold, proximity to the threshold alone does not imply a small sticking probability.