Approximate the atmosphere above as isothermal with constant gravity and atmospheric scale height , so
Vertical transport over one scale height has eddy mixing time
The chemical quench level satisfies . Since ,
Above this level, mixing is faster than reaction and freezes the deeper abundance of A. Larger moves the quench level deeper and raises . Important examples are carbon monoxide–methane quenching and nitrogen–ammonia quenching; phosphine destruction is another tracer of vertical quenching.