For a diffusion-controlled mushy layer of constant solid fraction , a sharp moving edge reduces the thermal heat equation to and the exterior solute diffusion equation to , where is the Lewis number. Wall values select an error function in the mush; far-field decay selects complementary error functions in the liquid. Continuity fixes their amplitudes in terms of the interfacial temperature and . The Stefan condition, solute conservation and marginal equilibrium at a mush-liquid boundary give three algebraic/transcendental equations for these two constants and . Derivation follows by and , followed by one integration . Dividing interface equations can discard degenerate branches, so the undivided equations must be retained when a denominator vanishes. Physical admissibility additionally requires and .
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