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For a double quantum dot, write $(n_L,n_R)$ for occupation. Tune a bias window allowing the cycle $(0,1)\to (1,1)\to (0,2)\to (0,1)$. Two electrons in the same lowest orbital must form a singlet state by the Pauli exclusion principle. The $(0,2)$ triplet requires an excited orbital, with an energy cost ${\Delta }_{ST}$ above the accessible window. Approximately spin-conserving tunnelling transfers $S(1,1)$ into $S(0,2)$, but cannot transfer $T(1,1)$ into that singlet. Once a triplet loads, transport stops until spin relaxation or mixing occurs: this is Pauli spin blockade. The reverse bias can avoid trapping in this sequence, producing rectification. Coulomb charging sets the allowed occupancies, but the extra blockade is a spin-selection restriction, not merely an energetically forbidden charge state.

magnetically driven spin-blockade lifting uses electron paramagnetic resonance. A transverse oscillating magnetic field drives spin transitions atFlipping one spin in $|\uparrow \uparrow ⟩$ gives $|\downarrow \uparrow ⟩=(|T_0⟩-|S⟩)/\sqrt{2}$, which has a singlet component and can resume charge transfer. A perfectly uniform simultaneous rotation of two identical spins preserves their triplet character; effective relative rotation needs unequal local resonance conditions or another singlet–triplet mixing mechanism. In a real GaAs double dot, inhomogeneous nuclear fields can supply that difference. Hyperfine mixing, spin-orbit effects, cotunnelling and ordinary relaxation also produce leakage and must be distinguished from driven resonance.

A demonstrated device used surface Ti/Au gates to define two dots in a GaAs/AlGaAs electron gas $90\mathrm{nm}$ below the surface. An insulated on-chip gold coplanar stripline supplied the oscillating magnetic field. With the dots biased in spin blockade, RF excitation produced current peaks at the two field polarities satisfying resonance. Peak positions varied linearly with frequency, giving $|g^{\ast }|=0.35\pm 0.01$. RF applied to a side gate instead gave negligible response, testing magnetic rather than electric excitation. Gate pulses and RF bursts further produced coherent spin-rotation oscillations in the charge readout.^[ref]

An ideal isolated resonant spin has Rabi oscillation probability $P_{\mathrm{flip}}(t)={\sin }^2({\Omega }_{R}t/2)$. For a linearly oscillating field of peak amplitude $B_{\mathrm{ac}}$, the rotating-wave convention is ${\Omega }_R=|g^{\ast }|{\mu }_B{B}_{\mathrm{ac}}/(2\hslash )$. Repeated initialization, isolated manipulation and blockade-sensitive readout can therefore map a damped oscillatory singlet yield into an average current. Nuclear fluctuations, readout rates and dephasing change the envelope and contrast; an ideal sine squared is not a reconstruction of experimental data. Compare RF on/off, resonance tracking with frequency, drive-amplitude dependence and detuning controls. Current enhancement alone does not prove coherent rotations; the pulse-duration oscillations provide the further time-domain test.

An electrostatically defined quantum dot uses depletion gates to confine a small island laterally in a two-dimensional electron gas. Two narrow barriers allow weak tunnelling to source and drain; a plunger gate tunes the island's electrochemical levels, and additional gates can form a double quantum dot. Adjusting the gates resolves successive charge states and eventually reaches the single-electron regime. An electrical dot is defined by confinement and tunnel coupling, not simply by the drawn metal area.

In a constant interaction model,Here $Q_g$ is gate-induced charge and $C_{\Sigma }$ total island capacitance. Successive additions cost $E_{\mathrm{add}}=e^2/C_{\Sigma }+{ϵ}_{N+1}-{ϵ}_N$, with spin, exchange and correlations modifying the orbital term. Coulomb blockade appears when no allowed charge transition lies in the source–drain energy window. Gate sweeps give charge steps and transport peaks; finite-bias Coulomb diamonds constrain charging and orbital energies under a stated bias convention. Resolved single-electron operation requires thermal and tunnel broadening smaller than the relevant addition energies.

Quantum-dot charge sensing avoids relying on a measurable current through a nearly isolated dot. A nearby quantum point contact biased on a sensitive conductance slope, or a single-electron transistor, responds capacitively when one electron enters or leaves the dot. A time trace of sensor current can therefore distinguish $N$ from $N-1$ and resolve individual tunnelling events. The sensor measures charge; a spin-dependent step is needed to measure spin.

For one electron, Zeeman splitting gives a lower and a higher spin level separated by $E_Z=|g^{\ast }|{\mu }_B|B|$. In energy-selective spin readout, initialize an empty dot and pulse both levels below the reservoir chemical potential to load one electron. Then move to a readout configurationAn electron in the higher state can tunnel out, temporarily leaving the dot empty, after which a lower-state electron can refill it. An electron initially in the lower state remains trapped. The charge sensor records a pulse for the first outcome and no escape pulse for the second. This is spin-to-charge conversion; it measures the spin projection along the field through a state-dependent tunnelling probability. A primary single-shot experiment uses this conversion with a quantum-point-contact charge detector.^[ref]

The readout window must be long enough to detect escape but short compared with excited-spin relaxation:Detector bandwidth must also resolve the empty-state dwell time before refilling. Thermal activation, relaxation before escape, missed fast events and sensor backaction cause errors. Since the excited electron can leave and be replaced, this simple sequence does not preserve an arbitrary initial spin state.

For coupled dots, label charge occupation by $(n_L,n_R)$. Gate-controlled detuning can make $(1,1)$ and $(0,2)$ accessible. Two electrons in the lowest orbital of one dot must form a singlet state; a triplet state requires a different orbital or another higher-energy configuration. Choose a measurement window where the $(0,2)$ singlet is available but the $(0,2)$ triplet is not. Thenunder spin-conserving tunnelling. The second process is forbidden by spin symmetry and the Pauli exclusion principle, producing Pauli spin blockade. Charge sensing distinguishes transfer from a blocked $(1,1)$ state. This measures singlet versus triplet content; without a reference spin or additional control it is not a measurement of each electron's absolute spin direction separately.

The exchange interaction in a double quantum dot provides control of these states. In an effective spin description,For a symmetric weak-tunnelling two-site model with onsite charging cost $U$, $J\simeq 4t_c^2/U$. Gates change tunnel coupling $t_c$ and detuning, allowing preparation and evolution followed by a charge-conversion measurement. Spin mixing from local magnetic-field differences or spin-orbit effects can lift blockade, so the sensing interval must be chosen before unwanted relaxation obscures the initial state. Single-dot readout uses spin-dependent escape; double-dot readout can use spin-dependent charge transfer. In both cases the measurable signal is a resolved charge change.

Suppression of charge transfer by spin symmetry and the Pauli exclusion principle. For a double quantum dot, a $(1,1)$ singlet state can enter the lowest $(0,2)$ singlet, whereas a $(1,1)$ triplet state is blocked if the required $(0,2)$ triplet lies above the accessible energy window. Spin mixing or relaxation can lift blockade.