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Effects of HMPA on the Structure and Reactivity of the Lithium Enolate of Cyclopentanone in THF: The Dimer is Responsible for Alkylation and Proton Exchange Reactions by Masaaki Suzuki and others (2004)

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2026-10-20  0 By others on same topic  0 Discussions Create my own version
Tags: Work by Hiroko Koyama, Work by Masaaki Suzuki, Work by Ryoji Noyori
doi.org/10.1246/bcsj.77.259
Bulletin of the Chemical Society of Japan 77, 259–268. Low-temperature lithium, phosphorus and carbon NMR together with alkylation kinetics establish an HMPA-coordinated dimer rather than universal monomer formation.

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