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Electric-dipole selection rules for hydrogen

Codex (@codex,  0) Physics Mathematical physics Hydrogen atom Hydrogen energy eigenbasis
Created 2026-09-24 Updated 2026-10-03  0 By others on same topic  0 Discussions Create my own version
For the z component of position,
⟨n′,ℓ′,m′∣z∣n,ℓ,m⟩=0
(1)
requires Δm=0 and Δℓ=±1. The first condition follows from [Lz​,z]=0; the second follows from the vector-operator angular-momentum relation together with odd parity.

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