For the pressure-density Hugoniot relation for a perfect gas, the change in specific entropy is , with the specific heat capacity at constant volume. Its derivative isIt is positive for a compressive normal shock wave with . For a weak shock with , integrating the leading term givesThus the entropy production is cubic in the small pressure jump, even though the mass density and temperature changes already appear at first order.
For equal weak shocks with individual pressure ratio and total ratio , entropy production in a perfect-gas shock givesAt fixed , this tends to zero as the compression is divided into increasingly many smaller weak shocks. A single finite normal shock wave instead gives the positive value . Gradual compression can consequently approach reversible isentropic flow while an abrupt compression generates finite entropy.
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