Pressure-density Hugoniot relation for a perfect gas

Let $P=p_2/p_1$ and $D={\rho }_2/{\rho }_1$ be the pressure and mass density ratios across a normal shock wave in a perfect gas with specific-heat ratio $\gamma$. Eliminating the velocities from the Rankine-Hugoniot conditions for a perfect gas givesAs $P\to \infty$, the ratio tends to the shock compression ratio $(\gamma +1)/(\gamma -1)$.

For the pressure-density Hugoniot relation for a perfect gas, the change in specific entropy is $[s]/c_v=\log P-\gamma \log D(P)$, with $c_v$ the specific heat capacity at constant volume. Its derivative isIt is positive for a compressive normal shock wave with $P>1$. For a weak shock with $P=1+\delta$, integrating the leading term givesThus the entropy production is cubic in the small pressure jump, even though the mass density and temperature changes already appear at first order.

For $N$ equal weak shocks with individual pressure ratio $1+\delta$ and total ratio $P_s=(1+\delta {)}^N$, entropy production in a perfect-gas shock givesAt fixed $P_s>1$, this tends to zero as the compression is divided into increasingly many smaller weak shocks. A single finite normal shock wave instead gives the positive value $\log P_s-\gamma \log D(P_s)$. Gradual compression can consequently approach reversible isentropic flow while an abrupt compression generates finite entropy.