For an initial pole of the Bloch sphere, one fixed-amplitude harmonic pulse detuned by transfers at most of the population. A pure equatorial state requires half transfer, so some pulse duration reaches the equator exactly when . Adjusting drive phase then selects its transverse azimuth. Exact inversion to the opposite pole is unavailable for nonzero detuning with that single fixed pulse. This is a restriction on the specified controls, rather than on composite-pulse or frequency-swept state preparation.
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