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Evaporative cooling of atoms selectively removes atoms with unusually high total energy, then elastic collisions rethermalize those remaining. Loss of particles alone is insufficient: the lost atoms must carry more than the mean energy per particle if the temperature is to fall. The process is open and dissipative, so it can increase the phase-space density of an atomic gas in the remaining sample while reducing its atom number. As the temperature falls, the cutoff must be lowered to keep replenishing a useful escaping tail; a fixed high cutoff eventually gives negligible evaporation.

An experimental sequence first loads laser-cooled atoms into a conservative trap and suppresses resonant-light heating. In a trap using magnetic trapping of neutral atoms, a radiofrequency evaporation knife drives a Zeeman splitting transition from a trapped weak-field-seeking state to an untrapped state on a surface where the splitting matches the radiofrequency photon energy. Only atoms energetic enough to reach that surface escape. Lowering the radiofrequency cutoff progressively removes less energetic atoms. Alternatively, lowering an optical dipole trap's depth permits energetic atoms to spill out. This changes confinement as well as the escape cutoff, so it can reduce the collision rate. Radiofrequency-selective evaporation and the need for favourable elastic-collision and background-loss rates are documented in the original condensate experiments.^[ref]

The elastic collision rate ${\Gamma }_{\mathrm{el}}\sim n{\sigma }_{\mathrm{el}}\bar{v}$ must be large enough for elastic rethermalization of a trapped atomic gas throughout evaporation, and much faster than unwanted loss and heating. A clean vacuum reduces background collisions; suitable trapping states suppress inelastic spin-changing loss, and density must not make three-body recombination dominant. The cutoff ramp should allow equilibration without taking so long that background losses dominate. A large evaporation truncation parameter $\eta ={ϵ}_{\mathrm{cut}}/(k_{B}T)$ selects energetically valuable atoms, but an excessively large value suppresses their escape rate. A very small value discards too many useful low-energy atoms. If elastic collisions become more frequent as evaporation proceeds, the resulting runaway evaporative cooling can improve efficiency; it is not automatic in a weakening optical trap.

The energy selectivity for evaporation to increase phase-space density can be made precise in a classical three-dimensional harmonic trap with fixed frequencies. Equipartition gives $E=3N{k}_{B}T$. If each escaping atom removes mean energy ${ϵ}_{\mathrm{ev}}$, energy balance is $dE={ϵ}_{\mathrm{ev}}dN$ with $dN<0$, soThe peak harmonic-trap phase-space density is $\mathcal{D}=N(\hslash \bar{\omega }/(k_{B}T){)}^3$. ThereforeCooling requires ${ϵ}_{\mathrm{ev}}>3k_{B}T$; increasing $\mathcal{D}$ despite atom loss requires the stronger condition ${ϵ}_{\mathrm{ev}}>4k_{B}T$. These inequalities assume rapid thermalization and no work from changing trap frequencies. They distinguish lower temperature from genuinely improved quantum degeneracy. Eventually quantum statistics and inelastic processes require a refinement of this classical estimate. Efficient evaporation combines energy-selective loss, rapid elastic redistribution, and low unwanted loss; it can bring a precooled gas to Bose-Einstein condensation.

evaporative cooling removes atoms selectively from the high-energy tail of a trapped gas. The remaining sample has less energy per atom; elastic collisions then redistribute energy and restore a thermal distribution at lower temperature. Random atom loss would generally remove average energy and would not provide the same cooling mechanism. Repeated energy selection and rethermalization, rather than one removal event, is the essential cycle.

Using the evaporation truncation parameter $\eta$, let the escape threshold be ${ϵ}_{\mathrm{cut}}=\eta k_{B}T$. As the gas cools, a fixed threshold is populated by fewer atoms, so evaporation stalls. In forced evaporative cooling the threshold is lowered during the sequence. In a magnetic trap, a radiofrequency evaporation knife flips trapped weak-field-seeking atoms into untrapped spin states where the Zeeman splitting matches the photon energy. Energetic atoms reach that resonance surface; sweeping the radiofrequency lowers the energy knife. In an optical dipole trap, lowering the trap depth offers a different implementation, although it usually also weakens confinement.

A simple evaporative cooling energy balance shows when atom loss is useful. For a classical gas in a three-dimensional harmonic trap of fixed frequencies, equipartition gives $E=3N{k}_{B}T$, counting both kinetic and potential energy. Suppose escaping atoms remove average energy ${ϵ}_{\mathrm{ev}}=(\eta +\kappa )k_{B}T$, with $\kappa$ a distribution-dependent excess above the threshold. For $dN<0$,Thus preferential removal cools when the removed energy exceeds $3k_{B}T$. More stringently, cooling must raise the phase-space density of an atomic gas, not merely lower the temperature:For this harmonic-trap phase-space density, with fixed geometric-mean trap frequency $\bar{\omega }$, $d\ln \mathcal{D}/d\ln N=1-3\alpha$. Therefore phase-space density rises during atom loss if $\alpha >1/3$. The numerical factors here belong to the stated harmonic-trap model, not every evaporative apparatus.

There must be enough elastic collisions to repopulate the tail: ${\Gamma }_{\mathrm{el}}\sim n\sigma \bar{v}$ should exceed damaging loss and heating rates, and the ramp should allow rethermalization. Increasing density can improve elastic collisions but also enhances inelastic and three-body losses. Very rapid removal can leave a nonequilibrium cloud; very slow removal exposes it to background-gas losses. Lowering an optical trap can reduce density and collision rate, so a falling temperature is not by itself evidence of efficient evaporation.

The dilute-gas condensation experiments made this tradeoff concrete. Eric A. Cornell and Carl Wieman's account explains how selective escape and contraction of a trapped cloud raise phase-space density, while the need for rapid two-body equilibration and slow three-body loss restricts usable density. It also describes expansion imaging as an experimental diagnostic.^[ref] Useful controls compare different knife ramps and hold times, measure both atom number and expansion temperature, and check trap-frequency calibration. Pure adiabatic expansion can cool without increasing phase-space density. Successful evaporation pays an atom-number cost to increase the remaining gas's phase-space occupancy.