With , and , helium-3 evolves as after deuterium elimination. The positive root is its unique attracting equilibrium for a fixed background. In the pp-I limit it reduces to , making equilibrium abundance strongly temperature dependent.
A small abundance displacement from the helium-3 equilibrium abundance obeys to linear order. Rapid relaxation relative to background evolution allows the abundance to track its equilibrium. If the equilibrium drifts, the displacement equation also contains . In the pp-I limit the rate is , so both production and destruction temperature dependences matter.
Equilibrium fails where the helium-3 relaxation time becomes comparable to stellar age. In a fixed-density pp-I scaling with reaction exponents four and sixteen, the equilibrium abundance scales as and the relaxation time as . Central normalization then places the transition near six million kelvin; using the full supplied exponential factors gives a somewhat higher estimate. A precise radius or temperature requires a stellar mass density/composition profile and the second branch contribution.
In the pp-I limit, helium-3 relaxation time is . At fixed proton number density, each thermonuclear reaction rate coefficient obeys . Taking their geometric mean gives the displayed relaxation ratio with . A local power-law approximation instead gives . These are estimates rather than a complete radial model: the proton number density, composition and pp-II branch change along a real stellar composition profile.
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