The Hughston--Jozsa--Wootters theorem says that two pure-state ensembles represent the same density operator exactly when their subnormalized state vectors are related by an isometry, or by a unitary after padding the shorter ensemble with zero vectors.
For the nonzero spectral decomposition , every pure-state quantum state ensemble of is specified by the displayed column linear isometry. To prove this, write . Positivity forces each into the support of , and the coefficients have orthonormal columns because . Conversely this column identity reconstructs ; the squared vector norms are the probabilities and sum to one. Complete the columns to unitary bases after adding zero ensemble vectors to obtain the usual unitary-mixing formulation.

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