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In Auger recombination an electron-hole pair annihilates while transferring its energy to another electron or hole rather than to an emitted photon. The hot recipient subsequently loses energy, commonly to phonons. In a simple nondegenerate carrier-density model the rate is $R_A=C_n{n}^{2}p+C_{p}n{p}^2$, with electron and hole number densities $n,p$ and material-dependent coefficients. This makes the process especially important at high carrier injection. It is the reverse type of energy transfer to impact ionization, although detailed thresholds and matrix elements depend on the bands.

A photodiode with a strong internal electric field in which photogenerated charge carriers undergo impact ionization, amplifying the initial signal. Linear multiplication below breakdown and saturated single-event operation above breakdown are distinct operating regimes. A single-photon avalanche diode uses the latter.

An electron-multiplying CCD adds a high-field multiplication register before the output amplifier. Impact ionization generates a large mean gain, reducing input-referred read noise but adding multiplication excess noise.

For quantum key distribution with Bell pairs, a source distributes one photon to Alice and its partner to Bob. One implementation is the Ekert protocol, using the spin singlet state $|{\psi }^{-}⟩=(|01⟩-|10⟩)/\sqrt{2}$. Each party independently chooses a polarization measurement setting after distribution. Equal settings give opposite outcomes; Bob reverses his outcome-to-bit assignment so these rounds give matching random bits. Other setting pairs test a Bell inequality, with ideal spin singlet state correlation $E(\mathbf{a},\mathbf{b})=-\mathbf{a}\cdot \mathbf{b}$ for the corresponding Bloch sphere axes. The optical polarizer angles correspond to twice those angles on the appropriate Bloch sphere great circle.

Over an authenticated public classical channel, Alice and Bob announce settings and detection times, select coincident detection rounds, and perform key sifting. They reveal a test sample to estimate the quantum bit error rate and the chosen Bell inequality signal, discarding all revealed bits. Excess disturbance causes an abort. Otherwise information reconciliation makes the retained strings agree and privacy amplification shortens them to remove an adversary's residual information, including information disclosed during reconciliation. The tested quantum entanglement supplies correlations unavailable to an independently prepared classical mixture; a security claim also requires stated detector and sampling assumptions.^[ref]

Each photon polarization analyzer uses a setting-dependent waveplate followed by a polarizing beam splitter. A single-photon detector on each output converts the routed photon into an electrical click, recording the outcome and its time. For example, a single-photon avalanche diode is a reverse-biased photodiode operated above breakdown: absorption creates a charge carrier, impact ionization triggers an avalanche, and the resulting pulse is registered. A quenching circuit lowers the bias to stop the avalanche and then resets the device. The detector dead time during recovery limits the count rate; dark counts produce false clicks, and imperfect detection loses rounds. The polarization information comes from the preceding analyzer, while the detector registers which output fired. Coincidence timing associates Alice's and Bob's records with the same emitted pair. ^[ref]

Generation increases the mobile electron or hole populations; interband excitation creates an electron-hole pair. Thermal excitation and absorbed photons are important sources, and impact ionization can multiply carriers in a strong field. Ordinary single-photon interband absorption needs enough photon energy to bridge the band gap, with the required momentum balance.

Electron-hole recombination removes a pair. Radiative electron-hole recombination emits a photon, with simple rate $Bnp$; trap-assisted electron-hole recombination uses localized defect levels and transfers energy to the lattice; Auger recombination transfers the electron-hole recombination energy to another carrier. The last process becomes especially important at high injection because its rate contains products such as $n^{2}p$ and $n{p}^2$. The detailed band structure and available defects determine which channel dominates.

At thermal thermodynamic equilibrium, generation and electron-hole recombination continue at equal rates. For the simple radiative model the net electron-hole recombination rate is $B(np-n_i^2)$, enforcing the semiconductor mass-action law. Under weak excitation with the majority density nearly fixed, an excess minority density often decays as $\Delta n(t)=\Delta n(0)e^{-t/\tau }$, defining its minority carrier lifetime.

A short light pulse followed by time-resolved electrical conductivity or luminescence measures the relaxation. Spatial diffusion, trapping and instrumental response must be separated from electron-hole recombination before identifying a single fitted decay constant with the intrinsic lifetime. These processes control photodetector response and light-emitting-device efficiency.

Let $\alpha ={\hslash }^2/(2m^{\ast })$, so the initial conduction-electron kinetic energy is $E_1=\alpha k_1^2$. In the normal momentum-conserving process with the final hole fixed at zero wavevector, the two final conduction electrons obey ${\mathbf{k}}_1={\mathbf{k}}_2+{\mathbf{k}}_3$. Their total kinetic energy satisfiesEnergy conservation for impact ionization is $E_1=E_g+\alpha (k_2^2+k_3^2)$. Consequently $E_1\ge E_g+E_1/2$, givingThe bound is attained when ${\mathbf{k}}_2={\mathbf{k}}_3={\mathbf{k}}_1/2$; opposite spins permit the two electrons to share that wavevector. Fixing the hole momentum is essential: a mobile final hole gives a different threshold. This is the threshold for impact ionization with a hole at zero momentum.

The two hot electrons subsequently redistribute energy by electron-electron collisions and transfer it to the lattice by electron-phonon scattering. Optical-phonon emission can provide large discrete losses while the electrons are hot; acoustic phonons dominate later small energy exchanges. Electron-electron collisions alone conserve the electron system's total energy and do not cool it into the lattice. The electron-hole pair eventually recombines radiatively or through nonradiative channels, such as defect-assisted recombination or Auger recombination. Recombination is distinct from the preceding intraband cooling.

A single-photon detector based on a reverse-biased photodiode operated above its breakdown voltage. A carrier generated by photon absorption can trigger a self-sustaining impact ionization avalanche. Quenching lowers the bias to stop that avalanche; recovery creates detector dead time. Random internally generated carriers can also trigger indistinguishable pulses, producing dark counts. Single-photon avalanche diodes ordinarily detect an event rather than resolve the incident photon number. ^[ref]