An apolar axis model with pair energy is invariant when each molecular representative is independently reversed. The vector average changes under these replacements, but the nematic order parameter made from second moments does not. In an unbiased statistical ensemble the vector average vanishes; an individual finite representative need not have zero average. For independently chosen signs of a perfectly aligned axis, . This distinguishes exact head-tail invariance of an observable from vanishing only after an average.[ref]
Lectures on Landau Theory of Phase Transitions by Peter D. Olmsted. §4.3, printed pp.10–11, molecular head-tail equivalence
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