For and latent-to-sensible heat ratio with , put , , and . The steady heat equation becomes in the mush and in the liquid. Matching temperature and heat flux at , with and liquid temperature far above, gives
The latent heat modifies the mush's effective thermal decay rate and therefore its thickness.
Use , , and , the latent-to-sensible heat ratio. Transforming the heat equation to the fixed apparatus frame and substituting Darcy flux gives the exact steady mush equation
For , the solid fraction is . Since , the latent term remains leading order, whereas the correction is small. Define . The large-concentration thermal profile of a pulled mush then obeys
With and in the liquid,
The thermal conductivity agrees on both sides and the solid fraction vanishes at the mush–liquid interface, so there is no jump in latent production there: continuity of heat flux gives . Thus
The boundary value determines , as calculated next. The crystal fraction is obtained from the previous part's formula, with the temperature field understood to this leading asymptotic accuracy.
Figure 1.
Temperature and crystal fraction in a steadily pulled mush
. The leading large-concentration temperature field matches smoothly to the liquid at the top of the mush. The crystal fraction tends to zero there; the remaining liquid freezes at the eutectic front at the bottom.
Melting raises permeability of a porous medium. An advancing protrusion therefore offers a less resistive path to hot liquid, attracting larger Darcy flux and receiving more heat. The resulting faster melting reinforces the protrusion: this is a reactive infiltration instability. A permeability decrease would reverse this feedback, while zero contrast gives no growth in this ideal model.
For positive contrast, the growth rate is proportional to transverse wavenumber, so the model has no finite fastest-growing wavelength. The latent-to-sensible heat ratio slows the front but supplies no short-wave cutoff. Finite thermal transport and a resolved melting zone can introduce a length scale; pore geometry eventually limits the continuum description. If interface curvature changes the equilibrium melting temperature through the Gibbs--Thomson relation, that can also oppose short-wave corrugations. The modified dispersion relation must include such effects before a preferred wavelength can be calculated; a length scale alone does not guarantee that every added mechanism selects one.