Past exam of the MPhil in micro- and nanotechnology enterprise course of the University of Cambridge / 2021 / Paper 1 / 6 / iii / Solution 2026-10-20
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Use a shaped nickel particle or nanowire as both sacrificial template and reducing agent. gold grows where nickel is consumed, allowing gold-coated particles, porous shells and, with suitable removal of the remaining nickel, hollow gold nanostructures. The original template controls the overall shape; the balance of dissolution, deposition and diffusion controls wall thickness and porosity.
A hollow product is not guaranteed simply by writing the reaction: deposition may seal a solid nickel core, whereas defects can maintain access to the interior and permit further replacement. Controlled composition and transport can give a progression from core–shell to porous or hollow structures. This is useful for high-surface-area electrodes, catalytic surfaces and plasmonic structures, while avoiding an electrical lead to every individual nanoparticle.
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