Although the pion has spin zero, one-pion exchange depends on nucleon spin and isospin and includes a nuclear tensor force. Shorter-range and multiple-nucleon interactions also matter. The scalar Yukawa potential isolates a range mechanism rather than specifying the complete nuclear force.[ref]
Modern Theory of Nuclear Forces by Evgeny Epelbaum and others. Modern Theory of Nuclear Forces, inspected preprint sections I.B and II.B, especially equation (2.11) and Fig. 12
The linear operator couples nucleon spin orientations to their separation direction . Here are Pauli matrices. A scalar radial potential energy alone omits this directional dependence.
An isotropic pure spatial state has zero electric quadrupole moment. The nonzero deuteron quadrupole moment consequently requires anisotropic structure. With ground-state , a nuclear tensor force can mix and waves while preserving total angular momentum and parity. A purely central spin-independent potential cannot produce this mixing. The inference of an orientation-dependent force was already explicit in 1939.[ref]
The Electric Quadrupole Moment of the Deuteron and the Field Theory of Nuclear Forces by Christian Møller and Léon Rosenfeld. Abstract and opening discussion, Nature 144, 476–477
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