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The residual strong interaction between nucleons. Its long-distance part involves pion exchange and depends on spin and isospin. It is distinct from directly exchanging gluons between color-singlet nucleons.

Why do protons and neutrons bind into an atomic nucleus, even though protons repel electrically? An attractive nuclear force can lower the total energy below that of separated nucleons, producing nuclear binding energy. The deuteron, containing one proton and one neutron, is the simplest such bound state.

In quantum chromodynamics, nucleons are composite colour singlets built from quarks and gluons. Their residual nuclear force has a longest-range strong contribution from one-pion exchange, with additional interactions at shorter distances.^[ref]

Although the pion has spin zero, one-pion exchange depends on nucleon spin and isospin and includes a nuclear tensor force. Shorter-range and multiple-nucleon interactions also matter. The scalar Yukawa potential isolates a range mechanism rather than specifying the complete nuclear force.^[ref]

The static one-pion exchange propagator gives a Yukawa potential proportional to $e^{-m_{\pi }cr/\hslash }/r$. Its characteristic range is therefore the Reduced Compton wavelength,This is an exponential falloff scale, not a sharp interaction cutoff. The ordinary Compton wavelength would introduce an unwanted factor $2\pi$.

The deuteron is the bound proton–neutron system. Its ground state has $J^P=1^{+}$ and isospin $T=0$, with binding energy approximately $2.225\mathrm{MeV}$ and no excited bound state. The small binding compared with characteristic nuclear energy scales produces an extended tail. With reduced mass $\mu \simeq m_N/2$, the asymptotic radial wavefunction decays as $e^{-\kappa r}$, whereThe decay length is not a sharp deuteron radius or the force range. It illustrates weak binding outside the region of strong attraction.

The observed total spin is consistent with aligned nucleon spins, $S=1$, and a predominantly $L=0$ spatial state, ${}^3{S}_1$. A central attraction identical in both spin–isospin channels would not distinguish this channel from a spin-singlet proton–neutron channel. In fact the triplet channel binds while the corresponding singlet channel does not. A realistic nuclear force must therefore distinguish these spin–isospin channels, for example through a term $V_{\sigma }(r){\mathbf{\sigma }}_p\cdot {\mathbf{\sigma }}_n$, whose eigenvalues are $+1$ and $-3$ in triplet and singlet states. The absence of a bound dineutron and diproton reinforces the need to distinguish channels; proton–proton Coulomb repulsion is an additional effect, not a complete explanation of the singlet nuclear interaction.

The clearest evidence against a purely central force is the nonzero electric quadrupole moment. A pure isotropic S-wave charge distribution would give zero. The deuteron quadrupole evidence for a tensor force instead points to a nuclear tensor force,It depends on how the spins point relative to the line joining the particles. It preserves total $J$ but couples orbital angular momenta differing by two, producingBoth terms have $J^P=1^{+}$, and their interference permits a quadrupole moment. The 1939 theoretical analysis explicitly connected the measured quadrupole moment with such directional dependence.^[ref]

The nuclear magnetic moment provides a second check. A pure aligned-spin S wave would give approximately ${\mu }_p+{\mu }_n\simeq 0.880{\mu }_N$, close to but larger than the observed deuteron value approximately $0.857{\mu }_N$. The discrepancy is consistent with non-S-wave structure and interaction-current corrections; it is not by itself a model-independent measurement of a D-state probability. The deuteron D-state admixture depends on the adopted Hamiltonian and electromagnetic current. The magnetic moments and mass differences used for these scales are tabulated physical constants.^[ref]

A useful schematic interaction therefore contains central, spin-dependent and tensor terms, and possibly spin–orbit terms in other channels. Long-range one-pion exchange naturally supplies a tensor component, with its finite range set by the pion mass. The deuteron establishes an attractive triplet channel and a noncentral tensor interaction; a spin-independent central potential is insufficient.

In 1935, Hideki Yukawa proposed a new massive exchange quantum to explain nucleon binding. His paper began with the inadequacy of an electron–neutrino exchange description of the binding strength. It then required a potential energy falling faster with distance than a Coulomb potential, introduced an exponentially decaying field, and related its inverse range to the exchange particle's rest mass. This was a theoretical proposal, not a detection with an apparatus of his own.^[ref]

The crucial idea is that a finite rest mass supplies a length scale even in empty space. In a scalar model, the static limit of a Klein-Gordon equation produces the modified Helmholtz equation. Its decaying Green's function gives the Yukawa potential. The derivation below isolates this range mechanism; one-pion exchange also carries spin and isospin structure.

The nuclear emulsion track experiment used developed photographic emulsions exposed to cosmic rays and inspected microscopically. Stopping pions gave daughter muon tracks with closely grouped ranges. Comparing penetrating muons with pion-induced nuclear breakup distinguished their interactions; this was not a direct static force measurement. The muon is a lepton, not Yukawa's strongly interacting meson.^[ref]