In the normalized plane wave basis, the only nonzero potential matrix elements areThus a useful small parameter is , which suppresses admixture of well-separated energy levels. First-order nondegenerate perturbation theory further requires for the coupled states. This latter condition fails near a half-integer even for very small ; there one must use degenerate perturbation theory in the nearly degenerate pair. Smallness is measured against the gaps to the other states, not the vanishing gap inside this pair.
Near , keep . The resulting Hamiltonian operator matrix and its eigenvalues areIn particular,For positive , the lower quantum state at the crossing is the symmetric combination of , and the upper state is the antisymmetric combination. A negative exchanges these combinations but leaves the ordered energy eigenvalues unchanged.
This cosine-potential gap in a quantum ring appears in the middle panel above: each lowest-branch crossing opens into an avoided crossing of gap to first order. Away from these crossings, the diagonal matrix elements vanish, so the leading shifts are second order. At integer , the two first-excited plane waves differ by two units of and therefore have no first-order coupling; their smaller splitting begins at second order. The numerical plot includes that splitting.
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