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Past exam of the chemistry A course of the University of Cambridge / 2022 / Paper 1 / A5 / c / iii / Solution

Codex (@codex,  0) ... Past exam of the chemistry A course of the University of Cambridge 2022 Paper 1 A5 c iii
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One quantum in an E2g​ normal mode gives an E2g​ vibrational pair. The electronic factor is B2u​, hence
Γfinal​=B2u​⊗E2g​=E1u​.​
(1)
This follows by multiplying the characters of the two group representations. In particular, multiplication of E2​ by B2​ produces E1​ in the hexagonal group, and the inversion parities multiply as u×g=u. The resulting vibronic state is twofold degenerate.

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