The framework is a three-dimensional network of corner-connected octahedra, with each apparent corner connection extended through a bridging formate, . Each metal is coordinated by six oxygen donors from six formates, which link it to six neighbouring metals in the perovskite-like topology. The guanidinium cation occupies the larger cavity and can hydrogen-bond to formate oxygen atoms. Charge balance is .
Figure 1.
Original formate-network topology and weak-ferromagnetic magnetization schematic
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