Take dimensionless spin operators and , with . The four wavefunctions are , , with
At zero field they form doublets at and . A transverse microwave magnetic field drives transitions. When , their positive resonance fields in ascending order are
They connect , , and , respectively. Thus
Here and the zero-field doublet gap is .
At lower frequency it is essential to use absolute energy gaps, not discard a transition after its levels cross. For , the distinct candidate positive fields are
The first two coincide when
This axial spin-three-halves resonance coincidence leaves two distinct resonance positions, at and , with two transitions superposed at the lower position. At there are also only two strictly positive-field lines, but an additional zero-field resonance remains; this is a different counting convention. Observable intensities also require thermal occupation of the relevant lower levels.
Figure 1.
Axial spin-three-halves levels and the three high-frequency resonance fields
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