Put . At , the free energy is . The four cyclic combinations in the supplied secular equation give the four-plane-wave splitting at a square-zone corner
For example, the normalized coefficient vectors in the source's cyclic basis are , , , and . Because , these are ordered as written: a lower singlet, a central doublet and an upper singlet. The sketch puts the and energies on one common scale; its representative negative couplings are stated in the caption.
Figure 1.
Common energy scale at the square-zone edge and corner, with illustrative couplings V10 = −1 eV and V11 = −0.2 eV
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