As the plasma cools through electron-positron annihilation, the pairs transfer their entropy to the coupled photons. Neutrinos have largely decoupled and do not share that heating in the instantaneous-decoupling approximation. Before annihilation the electromagnetic entropy count is
while after it . Conservation of electromagnetic comoving entropy, , gives the relative photon heating factor
Equivalently afterward. The exact count compares an asymptotic relativistic pair bath with the pair-free bath; at the supplied temperature some finite-electron-mass entropy loss has already begun.
The word “rises” requires care. The photons become hotter than an otherwise freely redshifting bath at the same scale factor; their absolute temperature need not rise during the expansion. In the smooth equilibrium process,
since the pair contribution grows with temperature. This monotonic photon cooling during pair annihilation is slower than while increases. The factor compares the photon temperature with the freely redshifting neutrino bath, not two consecutive absolute temperatures along the expanding history.

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