For unitary matrices, and . The adjoint matrix reverses the order of multiplication, so
Thus the product is unitary. Likewise , or this follows from invertibility in finite dimension.
Take the adjoint matrix of to obtain . Evaluating using this equation and gives
Hence . The proof does not assume that is a normal matrix or diagonalizable.
In general the spectrum of an adjoint matrix is the complex conjugate of the original spectrum, not necessarily the same set. The equality of the two sets in the question is an additional assumption, possible for a conjugation-invariant spectrum; the displayed orthogonality proof only uses the two stated eigenvalue equations.
A column of coordinates transforms as , because the columns of are the new orthonormal basis vectors expressed in the old coordinates. A symmetric unitary choice is
Its first and third columns are orthogonal eigenvectors of the block, with eigenvalues and respectively; its second column is the axis with eigenvalue . Direct multiplication checks , while the displayed entries give . The symmetry here means transpose symmetry, not Hermitian symmetry.

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