Consider the orientation-preserving affine group of the real line, realized as
The coordinates identify it smoothly with , so this Lie group is connected. Choose the Lie algebra element and the group element :
Direct matrix multiplication gives .
If a bi-invariant Riemannian metric existed, every conjugation map would be an isometry fixing the identity. Its differential there, the Adjoint representation of a Lie group, would preserve the positive-definite inner product at the identity. Thus
a contradiction since . Therefore this connected Lie group admits no bi-invariant Riemannian metric. This is the adjoint dilation obstruction to a bi-invariant Riemannian metric, an elementary alternative permitted by the question. The positive definite Riemannian metric interpretation matters; no claim about indefinite metrics is needed.

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