Past exam of the mathematics course of the University of Cambridge / 2005 / iii / Paper 81 / 4 / ii / d

Without surfactant, capillary pressure drives a surface flow towards a growing bulge. Advection compresses the insoluble surfactant in converging parts of that motion, increasing concentration and lowering surface tension. The resulting gradient supplies a tangential Marangoni stress that opposes the surface motion. This additional resistance slows capillary-driven redistribution of liquid even after the base-tension decrease has already been accounted for.

In the strong-elasticity limit, concentration gradients suppress tangential interface motion. The surface behaves as effectively immobile at leading order. Setting $u_s\approx 0$ in the velocity formula gives ${\sigma }_x\approx h{p}_x/2$, henceone-quarter of the clean shear-free mobility $h^3/(3\mu )$. This mobility reduction explains the quarter-rate limit; it slows the unstable capillary mode without removing the long-wave unstable band.