Density operator controllability cannot defeat unitary invariants: it grants access to the unitary orbit of a density operator, whose members have the same eigenvalues, rather than to every density operator. In the Hilbert-Schmidt inner product orthonormal normalization of this question,
Quantum Hamiltonian evolution preserves this norm, so the target is not reachable from the stated initial state. Equivalently, their values of purity of a density operator are and : the initial state is a mixed state and the target a pure state. Dissipation, an appropriate measurement protocol or an auxiliary system with additional resources would be needed to change the spectrum; freely controlling the closed-system Quantum Hamiltonian alone does not suffice.

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