A basis of Hermitian matrices is a real basis for the Hermitian subspace, but it also supplies a complex basis for all matrices. Indeed every operator has the decompositionwith Hermitian. Expand each in the given real basis, then combine their coefficients to expand . Orthogonality for the Hilbert-Schmidt inner product determines those complex coefficients uniquely:ConsequentlyIf is Hermitian, cyclicity of the trace givesThus its coordinate vector is real. The product need not itself be Hermitian; trace cyclicity is what justifies the conclusion.
A density operator is Hermitian, positive semidefinite and has trace one. Part (a) therefore makes all its coordinates real, and the identity basis vector fixes the final coordinate:The remaining basis vectors are traceless by orthogonality to . The Generalized Bloch representation is consequentlyUsing orthonormality to expand the squared Hilbert-Schmidt norm gives the purity bound for generalized Bloch vectors:If are its nonnegative eigenvalues, then andIt follows thatEquality requires every pairwise product to vanish, so exactly one eigenvalue equals one and all others are zero. Conversely, a rank-one projector has precisely that spectrum and attains equality. Thus equality holds exactly for a pure state. This normalization is different from the commonly used unit-radius qubit Bloch vector.
For , take the normalized Pauli operators as the traceless basis. The matrix associated with a vector is , where these basis matrices are the usual Pauli matrices divided by . Their multiplication relations giveAt radius , these eigenvalues are one and zero. Every sphere point therefore gives a positive rank-one projector. Any other orthonormal Hermitian basis merely changes the real coordinates by an orthogonal transformation, so the result is basis independent.
For every , choose a rank-one projector and consider the Hermitian trace-one matrixIts eigenvalues are once and with multiplicity . They sum to one and satisfyBy orthonormality its traceless coordinate vector has squared length , so it is on the specified sphere. But , so is not a density operator. Thus for , the pure states occupy a proper subset of the sphere; positivity excludes some of its points. In fact, this example is the antipodal Bloch vector to that of .
The usual assertion presumes . If the trivial dimension is admitted, the radius-zero sphere consists of the single coordinate point, also corresponding to the single pure state, so that dimension is an additional trivial exception.
Let denote the Lindbladian. Substituting and projecting with the Hilbert-Schmidt inner product givesFor the Quantum Hamiltonian term, cyclicity of the trace yieldsFor each Lindblad dissipator, the same cyclic rearrangement givesThese are the required coefficient matrices, so . They are real because both generators map Hermitian matrices to Hermitian matrices, whose coordinates are real by (a).
The trace of a commutator vanishes. AlsoThus the last row of is zero and . It is trace preservation, not preservation of the purity of a density operator, that produces this constant coordinate.
Write and . Since , the remaining coordinates obey the Affine Bloch equationBecause and , its offset can also be writtenIt vanishes for unital dynamics, but need not vanish for a general dissipative evolution.
For a Hermitian Quantum Hamiltonian, . ConsequentlySwapping changes the sign of the commutator, so . The generator is therefore real and antisymmetric. Its last column vanishes because the identity commutes with , so and the traceless block satisfies .
For constant , the Bloch vector evolves by with . Direct differentiation givesHence . Its determinant is continuously connected to one and cannot change between the two possible values , so . This proves that the evolution is a rotation in the special orthogonal group. A time-dependent Hermitian Quantum Hamiltonian has the same conclusion from .
These Hamiltonian rotations of Bloch vectors preserve the Euclidean norm and purity of a density operator. For , not every rotation of the ambient sphere is a physical unitary conjugation: the higher-dimensional positivity constraints and full spectrum of the density operator impose further restrictions.
Density operator controllability cannot defeat unitary invariants: it grants access to the unitary orbit of a density operator, whose members have the same eigenvalues, rather than to every density operator. In the Hilbert-Schmidt inner product orthonormal normalization of this question,Quantum Hamiltonian evolution preserves this norm, so the target is not reachable from the stated initial state. Equivalently, their values of purity of a density operator are and : the initial state is a mixed state and the target a pure state. Dissipation, an appropriate measurement protocol or an auxiliary system with additional resources would be needed to change the spectrum; freely controlling the closed-system Quantum Hamiltonian alone does not suffice.
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