For a degenerate Fermi gas, the Pauli exclusion principle restricts thermally changed occupations to an energy shell of width around the Fermi energy. The number of active Electrons is of order ; each carries an excitation energy of order . Thus the thermal energy grows as and the electronic heat capacity is proportional to .
More precisely, the fixed-particle-number Sommerfeld expansion givesHere is the total spin-summed density of states for the sample. For a three-dimensional parabolic band, , yieldingThe linear law concerns the electronic contribution; the low-temperature lattice heat capacity usually adds a term.
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