Past exam of the quantum condensed matter course of the University of Cambridge / 2022 / Section B / 4 / d / Solution

For independent electronic transitions, add the electric dipole moment responses:The positive constants $S_j$ include electron density and transition atomic oscillator strength. Each term adds an absorption peak to ${ϵ}_r^{\prime \prime }$ and a dispersive positive-to-negative contribution to ${ϵ}_r^{\prime }-1$, as in the middle row of the figure.

Between well-separated absorption lines, where the medium is transparent, the refractive index generally increases with frequency: $d{n}_r/d\omega >0$, or $d{n}_r/d\lambda <0$. This is normal dispersion. Near a resonance the real response turns down with increasing frequency, producing an interval of anomalous dispersion, $d{n}_r/d\omega <0$, accompanied by appreciable absorption. The absorptive and dispersive parts are linked by the Kramers-Kronig relations; the steep variation is not independent of the loss spectrum.