Treat the ions as a stationary neutralizing background and displace the cold electrons by a small longitudinal distance ξ. Their electric polarization is P=−neeξ, so the restoring electric field is E=−P/ϵ0=neeξ/ϵ0. The electron equation of motion isFor E=E0cosωpet, the oscillatory velocity is v=−eE0sinωpet/(meωpe). HenceThe longitudinal mode exchanges electron kinetic energy and electrostatic field energy like a harmonic oscillator, whose mean kinetic and potential energies are equal over a cycle. This is a time-average statement for the coherent oscillation, not thermal equipartition with kBT.
meξ¨=−eE=−ϵ0nee2ξ,ωpe=meϵ0nee2.
⟨uK⟩=21neme⟨v2⟩=4ϵ0E02=⟨2ϵ0E2⟩.
The Debye length is the distance over which a small, slowly varying electrostatic potential is screened by mobile thermal charges. For classical electrons in a weak potential ϕ, their Boltzmann distribution givesTake fixed singly charged ions of density n0. Then ρ=e(n0−ne)≃−n0e2ϕ/(kBT), and Poisson's equation outside a test charge becomes ∇2ϕ=ϕ/λD2, withThe screened point-charge potential is proportional to e−r/λD/r. The derivation assumes nondegenerate statistics and ∣eϕ∣≪kBT. Mobile ions would add their own contribution to λD−2; the expression here is the electron screening length.
ne(ϕ)=n0eeϕ/(kBT)≃n0(1+kBTeϕ).
λD=nee2ϵ0kBT.
For a nonrelativistic, three-dimensional ideal electron gas with spin degeneracy two,Dividing givesWrite the density-independent coefficient as K. From ℏωpe/EF=1.384, ne=(K/1.384)6. In this free-electron model,The result uses the stipulated energy ratio, rather than substituting a separately tabulated aluminium density or plasmon energy.
EF=2meℏ2(3π2ne)2/3,ωpe=meϵ0nee2.
EFℏωpe=ℏ2ϵ04e2me(3π2)−2/3ne−1/6.
ne≃1.59×1029m−3,EF≃10.69eV,ℏωpe≃14.79eV.
Using the replacement prescribed in the question, kBT→EF, givesThe number of electrons in a Debye sphere is consequentlyA useful check eliminates ne: with r=ℏωpe/EF and kF=(3π2ne)1/3, kFλD=2/r and ND=82/(9πr3).
λDprescribed=nee2ϵ0EF≃6.10×10−11m.
ND=34πneλD3≃0.151.
Having substantially fewer than one electron in this sphere shows that the classical many-particle Debye-screening picture is not applicable. It does not exclude collective plasmons in a degenerate electron gas. A proper zero-temperature Thomas-Fermi screening calculation uses ∂n/∂μ=3n/(2EF) and gives λTF2=2ϵ0EF/(3nee2), rather than literally replacing T by TF. The boxed count follows the source's stated prescription and exposes its physical limitation.
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