A scattering phase shift measures the change of a partial wave's outgoing phase relative to the free radial solution. For a real central potential and elastic scattering, probability conservation gives a unit-modulus Partial-wave S-matrix . Indeedso the incoming amplitude is unchanged and the outgoing one acquires .
Expanding an incident plane wave in Legendre polynomials and comparing the outgoing spherical wave givesUse and to remove cross terms:This is the elastic total scattering cross-section for the one-particle central-potential problem, with no identical-particle symmetrization factor.
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