Blackbody radiation is a thermal equilibrium gas of photons. In units with , its energy density isand its isotropic radiation pressure is .
In a large periodic box of volume , one polarization has wavevector modes per unit . The two transverse photon polarizations therefore giveafter integration over directions.
For an equilibrium system with energy and no conserved particle number, exactness of the entropy differential obtained from givesIf and as , integration gives .
Changing variables to in the Planck distribution giveswhere and are temperature-independent constants.
In an orthonormal tetrad, is the photon number density and is its number flux. Integrating the Boltzmann equation gives when momentum-boundary terms vanish. Collisionless propagation and photon-number-conserving scattering give zero divergence. Photon emission, photon absorption, electron-positron annihilation in cosmology, bremsstrahlung and double Compton scattering generally do not. This is a number current, not an electric charge current: photons are neutral.
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