A polyhedron with two congruent parallel polygonal bases whose corresponding vertices are joined by parallel edges. A right prism has edges between the bases perpendicular to their planes. The optical use of a transparent prism is a separate application of this geometric shape.
Consider a homogeneous optical prism with apex angle , in the same exterior medium on both sides. Let be the relative refractive index, the inside refractive index divided by the exterior refractive index. For a ray crossing both faces in the usual principal section, the internal angles obey . Snell's law gives external incidence and emergence angles and , where
The deviation is . On the interior of this interval,
Thus convexity gives . The minimum occurs for the symmetric path , yielding
A path with nongrazing entry and exit requires . Equality describes only a grazing limit; a larger value prevents transmission across both faces in this section. The condition matters: if , the sign of reverses, so the symmetric path maximizes this signed deviation instead. Measuring the minimum deviation therefore determines for an ordinary glass-in-air optical prism.
For a prism in air with fixed apex angle , Snell's law gives , and . The exit angle is relative to the moving exit-face normal; the deviation is relative to the incoming beam. Rotating the prism while keeping the incident beam fixed changes the laboratory outgoing direction by . Steering the incoming beam while fixing the prism instead changes it by . These are distinct experiments; emergence and total-internal-reflection conditions must also be checked.
A prism with two hexagonal faces and six quadrilateral side faces. Its twelve vertices and eighteen edges provide an alternating aluminium–oxygen cage model when the graph is coloured bipartitely.

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