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The zero-field energy levels here are averaged over hyperfine structure; $h$ is the Planck constant. Electron self-energy and vacuum polarization produce radiative corrections. Self-energy describes the bound Electron's radiative interaction with its own electromagnetic field. Precision predictions also include nuclear recoil and proton charge radius effects; assigning recoil terms to the reference or Lamb shift is convention-dependent. A finite proton charge radius changes binding independently of radiative effects.^[ref]

A vacuum-electric field “jiggling” picture motivates one contribution, not every hydrogen atom energy correction.

A spatial charge density describing the electric charge inside an atomic nucleus. In a static description centered on the nucleus, normalize it bywhere $Z$ is the atomic number and $e>0$ the elementary charge. A nuclear charge distribution is an average over a nuclear quantum state, rather than a photograph of immobile protons. Even when the average has spherical symmetry, individual nucleons need not sit on spherical shells. The proton charge radius and the internal charge density of the neutron also contribute: a distribution of pointlike proton centers is an approximation to a nuclear charge distribution, not its definition.

The experimental attraction is that an Electron probes electric charge through the electromagnetic interaction, without itself feeling the nuclear force. Varying its momentum transfer changes the spatial scale tested. Long wavelengths mainly constrain a nuclear charge radius; shorter wavelengths can distinguish a diffuse edge from a sharper one through diffraction. Recovering the entire nuclear charge distribution from a finite range of noisy scattering data remains an inverse problem.

The root mean square radius of a nuclear charge distribution, referred to its center. Define its charge-weighted second moment byFor a spherical charge density with finite fourth moment, insert the Taylor series $\sin u/u=1-u^2/6+O(u^4)$ into the nuclear charge form factor:Thus a radius is a low-momentum transfer slope, not necessarily the position of a sharp edge. In this real static model,The factor of two between the slopes of $F$ and $|F{|}^2$ matters when interpreting a differential scattering cross-section. A proton charge radius is the corresponding size concept for the proton; the spatial arrangement of many nucleons introduces an additional scale in a heavier atomic nucleus.