Quark chiral condensate ($⟨\bar{q}q⟩\ne 0$)

A nonzero vacuum value of the scalar quark density breaks the massless nonsinglet chiral symmetry to its diagonal vector subgroup. Indeed, the nonsinglet axial charge algebra of quark densities gives $⟨[Q_{5,a},P_b]⟩=-i{\delta }_{ab}⟨\bar{q}q⟩$, whereas invariance of the vacuum under every conserved axial charge would make these expectations vanish. The three broken generators produce three massless Goldstone bosons in the exact chiral limit. Small equal quark masses explicitly break that symmetry and turn the pions into pseudo-Goldstone bosons, with squared masses linear in the quark mass at leading order.