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Alpha decay releases energy in charged particles with short stopping ranges in matter, so much of their kinetic energy becomes local heat. An appropriate radioisotope thermoelectric generator can use a predictable radioactive decay heat source without requiring sunlight or a sustained nuclear chain reaction. Low penetrating photon and neutron output is desirable, but being an alpha emitter does not by itself establish the complete radiation spectrum.

The isotope's half-life must suit the mission. A short half-life gives high initial specific activity but a rapid decline in useful thermal power; a much longer one gives a steadier output but less activity per atom. Selection also depends on recoverable decay energy, specific power, daughter emissions, chemical and thermal stability, compatibility with the power-conversion system, availability and cost. Practical containment and radiological acceptability remain separate system-level requirements.

A thermoelectric generator converts a temperature difference into electrical output through the Seebeck effect; not all decay heat becomes electricity. NASA's operational account describes this heat-to-electricity distinction and the need to match source lifetime to long space missions.^[ref]

For the assumed three-half-life mission, the thermal power falls by a factor of eight. That large decline is the important disadvantage of this particular half-life even though the initial specific thermal power is high.