Saul Dushman Created 2026-10-18 Updated 2026-11-05
Saul Dushman investigated electron emission from metals as a function of temperature. Thermal emission connects the population of sufficiently energetic electrons with the energy required to escape a surface.
The strong temperature dependence makes the phenomenon useful in electron sources, while the surface state and work function affect quantitative interpretation.[ref]
Physical chemistry.[ref]
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Thermionic Richardson constant Created 2026-10-18 Updated 2026-10-20
The coefficient has dimensions of electric current density divided by squared temperature. For ideal nonrelativistic particles with the free electron mass, two spin states, a planar uniform surface, and unit escape transmission, the thermionic tail-flux derivation giveswhere is the positive elementary charge and is the Planck constant. The two area units differ by a factor of . A fitted need not equal : reflection at the surface, the electronic band structure, and uncertain emitting area affect the inferred coefficient. A constant escape transmission would give in this simple model; an energy-dependent transmission generally requires an integral instead.
The name joins Owen Willans Richardson with Saul Dushman. Dushman's 1923 paper develops a thermodynamic treatment of electron emission analogous to evaporation and evaluates the prefactor using quantum ideas.[ref]
Electron Emission from Metals as a Function of Temperature by Saul Dushman. Abstract, general equation and theoretical evaluation of A