A scattering phase shift measures the change of a partial wave's outgoing phase relative to the free radial solution. For a real central potential and elastic scattering, probability conservation gives a unit-modulus Partial-wave S-matrix . Indeed
so the incoming amplitude is unchanged and the outgoing one acquires .
Expanding an incident plane wave in Legendre polynomials and comparing the outgoing spherical wave gives
Use and to remove cross terms:
This is the elastic total scattering cross-section for the one-particle central-potential problem, with no identical-particle symmetrization factor.
Spherical wave 2026-10-20
For time dependence , the three-dimensional radial solutions and describe outgoing and incoming spherical waves away from the origin. Their inverse-radius amplitudes make their flux through spheres independent of radius. They form the asymptotic radial ingredients of partial-wave scattering.